Squealing is caused when two parts are moving at different speeds but touching each other. So, if it's when you start to pull away it is most probably one of 3 things; loose fan belt (but may squeal any time, not just under acceleration), brake pad/shoe locking up, or clutch (unusual these days but possible with older model cars).
Most commonly it's the fan belt slightly loose or worn. If you rev the engine with the clutch down a few times and it stops, probably this. If it seems to be coming from one corner of the car and the engine is heating up faster than usual in traffic, could be a sticky brake. If it's been happening for a while, it probably won't be the clutch ;-)
I really don't want to sound patronising, but if you're asking the question here you probably don't know enough to repair it yourself if it's the last 2. A fan belt is a relatively easy job with a workshop manual to hand, but if you're a beginner it might be wise to go to a local mechanic. If you're interested in learning, some of them may let you get in amongst the action and let you watch them do the job. If money is tight, ask around at the local car spares shop, they often know people who will do it a bit cheaper.
Good luck!
Most commonly it's the fan belt slightly loose or worn. If you rev the engine with the clutch down a few times and it stops, probably this. If it seems to be coming from one corner of the car and the engine is heating up faster than usual in traffic, could be a sticky brake. If it's been happening for a while, it probably won't be the clutch ;-)
I really don't want to sound patronising, but if you're asking the question here you probably don't know enough to repair it yourself if it's the last 2. A fan belt is a relatively easy job with a workshop manual to hand, but if you're a beginner it might be wise to go to a local mechanic. If you're interested in learning, some of them may let you get in amongst the action and let you watch them do the job. If money is tight, ask around at the local car spares shop, they often know people who will do it a bit cheaper.
Good luck!